Jolie met Billy Bob Thornton on the set of the 1999 film Pushing Tin, in which they played husband and wife. Both were in other relationships, with Thornton reportedly engaged to actress Laura Dern. Angelina Jolie is an American actress, screenwriter, and director. She is one of the most sought-after actresses in the industry. Her career has accumulated many awards, including multiple Academy and Golden Globe Awards, a testament to her stellar performances. Angelina Jolie, who is now single, has been married three times since 1996. Find out about her ex-husbands here. Angelina Jolie, 46, may get a lot of attention for her acting talents, but... Hollywood’s legend Angelina Jolie doesn't need an introduction. She was married 3 times and has six kids: three sons and three daughters.