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alignment (countable and uncountable, plural alignments ) An arrangement of items in a line. The process of adjusting a mechanism such that its parts are aligned ; the condition of having its parts so adjusted. An alliance of factions. CSS Centering Elements With CSS, you can center elements (horizontally, vertically, or both) with several methods, depending on the type of element. Definition of alignment noun in Oxford Advanced Learner's Dictionary. Meaning, pronunciation, picture, example sentences, grammar, usage notes, synonyms and more. Alignment is a term that can refer to various concepts and phenomena in different fields and disciplines. It can mean a co-linear arrangement, a similarity, a process, a system, or a perspective.